Environment and Interdisciplinary Development

Application of Iron, Aluminum and Copper Composites to Remove High Concentration of Chromium in Water

Document Type : Original Article

Authors

Maedeh Parichehre 1
Fardin Sadeghzadeh 2
Bahi Jalili 2
Mohammad Ali Bahmanyar 2
Abd Wahid Samsuri 3

1 PhD candidate of Soil Fertility and Biotechnology Management, Sari University of Agricultural Sciences and Natural Resources, Sari, Iran

2 Department of Soil Science and Engineering, Sari University of Agricultural Sciences and Natural Resources, Sari, Iran

3 Department of Land Management, Faculty of Agriculture, University Putra Malaysia, Selangor, Malaysia

https://doi.org/10.22034/envj.2023.389609.1284
Abstract
Introduction: The increase of various industries and the ever-increasing growth of the population of the planet have caused all kinds of contamination in the environment. One of the most important contaminants in water, which has many risks for human health and living organisms and important environmental risks, is anionic compounds in high concentration. Chromium is one of these contaminants that causes contamination in the environment and brings many risks to human health and other living organisms. Various methods have been evaluated to remove heavy metals from water, which often include chemical or energy-intensive processes. Therefore, it is important to modify these sources with the help of affordable adsorbents and with low energy consumption. Previous studies showed that biochar, metal-coated biochars and carbon-metal composites are highly effective in removing chromium contaminants with a concentration of 20 mg/liter from water, but so far the effect of these adsorbents on removing this anionic contaminant in high concentrations has not been investigated.
Materials and Methods: In this research, the efficiency of different adsorbents (biochar, copper-coated biochar, aluminum-coated biochar, iron-coated biochar, biochar-copper composite, biochar-aluminum composite and biochar-iron composite) on the removal of chromium, with a concentration of 300 mg per liter, from water was investigated. Metal-coated biochars were prepared from the combination of metals (copper, iron and aluminum) with a concentration of 10000 mg/kg with biochar produced at 600 degrees Celsius and various biochar-metal composites were prepared from the combination of these metals with rice straw and then the samples were pyrolyzed at 600 degrees Celsius. In order to determine the efficiency of the adsorbents, 0.5 grams of each adsorbent was mixed with 40 ml of chromium solution with a concentration of 300 mg/l and pH= 6 and shaken for three hours until they reached equilibrium. Then the samples were centrifuged for 5 minutes at 6000 rpm and after the filtration, the final concentration of the contaminant was obtained and the percentage of chromium removal was calculated.
Results: The results of the present study showed that all of the applied adsorbents were effective in removing high concentrations of chromium from water. The lowest removal rate of this contaminant was related to the biochar sample, which only removed 15.28% of this contaminant from water; And the highest amount of removal was achieved using iron composite, which removed 44.45% of the contaminant from the aqueous solution. According to the results of this research, it can be observed that coating biochar and rice straw with metals has been able to increase the efficiency of this adsorbent in removing chromium from water. For example, iron composite and iron-coated biochar were able to remove 44.45 and 30.86% of chromium contaminant from the aqueous solution, respectively, while rice straw biochar was only able to remove 15.28% of this contaminant from water.
Discussion: The results of present study showed that iron coated biochar and biochar-iron composite had more ability to remove chromium contaminant from aqueous solution than other metal coated biochars and biochar-metal composites and were able to perform more successfully. Therefore, the use of these adsorbents can be effective in the treatment of chromium-contaminated water.

Keywords

Adsorption
Anionic Contaminant
Biochar
Biochar-Metal Composite
Metal Coated Biochar

Subjects

  1. Ahmad, M., Rajapaksha, A.U., Lim, J.E., Zhang, M., Bolan, N., Mohan, D., Vithanage, M., Lee, S.S. and Ok, Y.S., 2014. Biochar as a sorbent for contaminant management in soil and water: a review. Chemosphere, 99, 19-33.
  2. Choppala, G., Bolan, N., Megharaj, M., Chen, Z. and Naidu, R., 2012. The influence of biochar and black carbon on reduction and bioavailability of chromate in soils. Journal of Environmental Quality, 41(4), 1175-1184.
  3. Fendorf, S., Wielinga, B.W. and Hansel, C.M., 2000. Chromium transformations in natural environments: the role of biological and abiological processes in chromium (VI) reduction. International Geology Review, 42(8), 691-701.
  4. Fuchs, M.R., Garcia-Perez, M., Small, P. and Flora, G., 2014. Campfire lessons: Breaking down the combustion process to understand biochar production and characterization. The Biochar Journal.
  5. Gong, X., Huang, D., Liu, Y., Zeng, G., Wang, R., Wan, J., Zhang, C., Cheng, M., Qin, X. and Xue, W., 2017. Stabilized nanoscale zerovalent iron mediated cadmium accumulation and oxidative damage of Boehmeria nivea (L.) Gaudich cultivated in cadmium contaminated sediments. Environmental science & technology, 51(19), 11308-11316.
  6. Hoseinzadeh, E., Rezaee, A., Shams Khorramabadi, G., Azizi, S. and Yousefzadeh, A., 2013. Evaluation of Photocatalytic Convertion of Hexavalent Chromium (Cr(VI)) to Trivalent Chromium (Cr(III)) in the presence of Zinc Oxide Nanoparticle from Aqueous Solution [Research(Original)]. Journal of Mazandaran University of Medical Sciences, 22(1), 116-132. http://jmums.mazums.ac.ir/article-1-3438-fa.html
  7. Huang, D., Liu, C., Zhang, C., Deng, R., Wang, R., Xue, W., Luo, H., Zeng, G., Zhang, Q. and Guo, X., 2019. Cr (VI) removal from aqueous solution using biochar modified with Mg/Al-layered double hydroxide intercalated with ethylenediaminetetraacetic acid. Bioresource Technology, 276, 127-132.
  8. IBI. 2012. Standardized product definition and product testing guidelines for biochar that is used in soil
  9. Ikegami, K., Hirose, Y., Sakashita, H., Maruyama, R. and Sugiyama, T., 2020. Role of polyphenol in sugarcane molasses as a nutrient for hexavalent chromium bioremediation using bacteria. Chemosphere, 250, 126267.
  10. Jacob, L., Joseph, S. and Varghese, L.A., 2020. Polysulfone/MMT mixed matrix membranes for hexavalent chromium removal from wastewater. Arabian Journal for Science and Engineering, 45, 7611-7620.
  11. Kambo, H.S. and Dutta, A., 2015. A comparative review of biochar and hydrochar in terms of production, physico-chemical properties and applications. Renewable and Sustainable Energy Reviews, 45, 359-378.
  12. Kumar, A., Singh, E., Khapre, A., Bordoloi, N. and Kumar, S., 2020. Sorption of volatile organic compounds on non-activated biochar. Bioresource Technology, 297, 122469.
  13. Kumar, N., Kardam, A., Jain, V. and Nagpal, S., 2020. A rapid, reusable polyaniline-impregnated nanocellulose composite-based system for enhanced removal of chromium and cleaning of waste water. Separation Science and Technology, 55(8), 1436-1448.
  14. Kumar, P.S., Korving, L., van Loosdrecht, M.C. and Witkamp, G.J., 2019. Adsorption as a technology to achieve ultra-low concentrations of phosphate: Research gaps and economic analysis. Water Research X, 4, 100029.
  15. Li, R., Wang, J.J., Gaston, L.A., Zhou, B., Li, M., Xiao, R., Wang, Q., Zhang, Z., Huang, H. and Liang, W., 2018. An overview of carbothermal synthesis of metal–biochar composites for the removal of oxyanion contaminants from aqueous solution. Carbon, 129, 674-687.
  16. Mohamed, A.K. and Mahmoud, M.E., 2020. Nanoscale Pisum sativum pods biochar encapsulated starch hydrogel: a novel nanosorbent for efficient chromium (VI) ions and naproxen drug removal. Bioresource Technology, 308, 123263.
  17. Mohan, D., Rajput, S., Singh, V.K., Steele, P.H. and Pittman Jr, C.U., 2011. Modeling and evaluation of chromium remediation from water using low cost bio-char, a green adsorbent. Journal of hazardous materials, 188(1-3), 319-333.
  18. Nagara, V.N., Sarkar, D., Elzinga, E.J. and Datta, R., 2022. Removal of heavy metals from stormwater runoff using granulated drinking water treatment residuals. Environmental Technology & Innovation, 28, 102636.
  19. Pan, J., Jiang, J. and Xu, R., 2013. Adsorption of Cr (III) from acidic solutions by crop straw derived biochars. Journal of environmental sciences, 25(10), 1957-1965.
  20. Parichehre, M., Sadeghzadeh, F., Jalili, B., Bahmanyar, M.A. and Samsuri, A.W., 2022. Removal of Direct Blue 71 and chromium from aqueous solutions by metal coating organic adsorbents, metal coating biochar and biochar-metal composite. Water and Soil Management and Modeling. https://doi.org/10.22098/MMWS.2022.11696.1158. (in persian)
  21. Parichehre, M., Sadeghzadeh, F., Jalili, B., Bahmanyar, M.A. and Samsuri, A.W., 2023. Determining the Efficiency of carbonaceous adsorbents in Removing Chromium (VI) from Aqueous Solution. Journal of water and wastewater. https://doi.org/10.22093/WWJ.2023.371326.3306. (in persian)
  22. Patra, C., Shahnaz, T., Subbiah, S. and Narayanasamy, S., 2020. Comparative assessment of raw and acid-activated preparations of novel Pongamia pinnata shells for adsorption of hexavalent chromium from simulated wastewater. Environmental Science and Pollution Research, 27, 14836-14851.
  23. Rahman, Z. and Singh, V.P., 2019. The relative impact of toxic heavy metals (THMs) (arsenic (As), cadmium (Cd), chromium (Cr)(VI), mercury (Hg), and lead (Pb)) on the total environment: an overview. Environmental monitoring and assessment, 191, 1-21.
  24. Revathi, M., Sivagaami Sundari, G., Ahmed Basha, C., Alam, M., Sagadevan, S. and Ahmad, N., 2020. Reclamation of hexavalent chromium from electroplating effluents by electroextraction. Journal of nanoscience and nanotechnology, 20(10), 6547-6554.
  25. Reyes-Serrano, A., López-Alejo, J.E., Hernández-Cortázar, M.A. and Elizalde, I., 2020. Removing contaminants from tannery wastewater by chemical precipitation using CaO and Ca (OH) 2. Chinese Journal of Chemical Engineering, 28(4), 1107-1111.
  26. Sakthivel, A., Thangagiri, B., Jeyasubramanian, K., Raja, J.D., Prabhahar, R.S.S., Nayagi, S.P.B. and Krishnamurthy, N., 2021. Switching the hydrophobic Neyveli lignite into hydrophilic type by surface modification and its subsequent use for removing Cr (VI)/F− from artificial pollutant. Fuel, 298, 120787.
  27. Samsuri, A., Sadegh-Zadeh, F. and Seh-Bardan, B., 2014. Characterization of biochars produced from oil palm and rice husks and their adsorption capacities for heavy metals. International Journal of environmental science and technology, 11(4), 967-976.
  28. Shakya, A. and Agarwal, T., 2019. Removal of Cr (VI) from water using pineapple peel derived biochars: Adsorption potential and re-usability assessment. Journal of molecular liquids, 293, 111497.
  29. Søberg, L.C., Winston, R., Viklander, M. and Blecken, G.T., 2019. Dissolved metal adsorption capacities and fractionation in filter materials for use in stormwater bioretention facilities. Water Research X, 4, 100032.
  30. Tan, X., Liu, Y., Zeng, G., Wang, X., Hu, X., Gu, Y. and Yang, Z., 2015. Application of biochar for the removal of pollutants from aqueous solutions. Chemosphere, 125, 70-85.
  31. Tareq, R., Akter, N. and Azam, M.S., 2019. Biochars and biochar composites: Low-cost adsorbents for environmental remediation. In Biochar from biomass and waste (pp. 169-209). Elsevier.
  32. Thangagiri, B., Sakthivel, A., Jeyasubramanian, K., Seenivasan, S., Raja, J.D. and Yun, K., 2022. Removal of hexavalent chromium by biochar derived from Azadirachta indica leaves: batch and column studies. Chemosphere, 286, 131598.
  33. USDA. and NRCS., 2007. Statistix8 and user guid for the plant material program T version 2. 1-80.
  34. Wang, H., Song, X., Zhang, H., Tan, P. and Kong, F., 2020. Removal of hexavalent chromium in dual-chamber microbial fuel cells separated by different ion exchange membranes. Journal of hazardous materials, 384, 121459.
  35. Wang, H., Wang, S. and Gao, Y., 2020. Cetyl trimethyl ammonium bromide modified magnetic biochar from pine nut shells for efficient removal of acid chrome blue K. Bioresource Technology, 312, 123564.
  36. Wang, J., Sun, T., Saleem, A. and Chen, Y., 2020. Enhanced adsorptive removal of Cr (VI) in aqueous solution by polyethyleneimine modified palygorskite. Chinese Journal of Chemical Engineering, 28(10), 2650-2657.
  37. Wang, L., Chen, M., Li, J., Jin, Y., Zhang, Y. and Wang, Y., 2020. A novel substitution-based method for effective leaching of chromium (III) from chromium-tanned leather waste: The thermodynamics, kinetics and mechanism studies. Waste Management, 103, 276-284.
  38. Wang, X.S., Chen, L.F., Li, F.Y., Chen, K.L., Wan, W.Y. and Tang, Y.J., 2010. Removal of Cr (VI) with wheat-residue derived black carbon: reaction mechanism and adsorption performance. Journal of hazardous materials, 175(1-3), 816-822.
  39. Wang, Z., Shen, Q., Xue, J., Guan, R., Li, Q., Liu, X., Jia, H. and Wu, Y., 2020. 3D hierarchically porous NiO/NF electrode for the removal of chromium (VI) from wastewater by electrocoagulation. Chemical Engineering Journal, 402, 126151.
  40. Xiang, W., Zhang, X., Chen, J., Zou, W., He, F., Hu, X., Tsang, D.C., Ok, Y.S. and Gao, B., 2020. Biochar technology in wastewater treatment: A critical review. Chemosphere, 252, 126539.
  41. Xue, W., Huang, D., Zeng, G., Wan, J., Zhang, C., Xu, R., Cheng, M. and Deng, R., 2018. Nanoscale zero-valent iron coated with rhamnolipid as an effective stabilizer for immobilization of Cd and Pb in river sediments. Journal of hazardous materials, 341, 381-389.
  42. Yao, F., Jia, M., Yang, Q., Luo, K., Chen, F., Zhong, Y., He, L., Pi, Z., Hou, K. and Wang, D., 2020. Electrochemical Cr (VI) removal from aqueous media using titanium as anode: Simultaneous indirect electrochemical reduction of Cr (VI) and in-situ precipitation of Cr (III). Chemosphere, 260, 127537.
  43. Yao, Y., Gao, B., Inyang, M., Zimmerman, A.R., Cao, X., Pullammanappallil, P. and Yang, L., 2011. Removal of phosphate from aqueous solution by biochar derived from anaerobically digested sugar beet tailings. Journal of hazardous materials, 190(1-3), 501-507.
  44. Yi, Y., Tu, G., Zhao, D., Tsang, P.E. and Fang, Z., 2020. Key role of FeO in the reduction of Cr (VI) by magnetic biochar synthesised using steel pickling waste liquor and sugarcane bagasse. Journal of Cleaner Production, 245, 118886.
  45. Ying, Z., Ren, X., Li, J., Wu, G. and Wei, Q., 2020. Recovery of chromium (VI) in wastewater using solvent extraction with amide. Hydrometallurgy, 196, 105440.
  46. Zameni, L., 2016. Leaching in a soil amended with biochar and Fe-coated biochar Nitrate Sari Agricultural Sciences and Natural Resources University (in persian)].
  47. Zhang, M., Gao, B., Yao, Y., Xue, Y. and Inyang, M., 2012. Synthesis, characterization, and environmental implications of graphene-coated biochar. Science of the Total Environment, 435, 567-572.
  48. Zheng, Y., Zimmerman, A.R. and Gao, B., 2020. Comparative investigation of characteristics and phosphate removal by engineered biochars with different loadings of magnesium, aluminum, or iron. Science of the Total Environment, 747, 141277.
  49. Zou, H., Zhao, J., He, F., Zhong, Z., Huang, J., Zheng, Y., Zhang, Y., Yang, Y., Yu, F. and Bashir, M.A., 2021. Ball milling biochar iron oxide composites for the removal of chromium (Cr (VI)) from water: Performance and mechanisms. Journal of hazardous materials, 413, 125252.
Environment and Interdisciplinary Development
Volume 8, Issue 79
Spring 2023
Pages 66-78

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